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I just stick the LED to a small square of double-sided tape on my workbench. Then apply a tiny drop of that gooey paste flux they used to sell at Radio Shack to the pad, then touch for an instant with the point of the soldering iron, already having a little drop of solder hanging on the tip. That immediately tins the pad on the LED. Do the same thing for the wire.Then place the wire in position, sticking it to the double-sided tape so the stripped, tinned wire end is right against the LED pad and won't move. Now get a tiny drop of solder on the soldering iron tip again, and touch it to the joint. The wire should bond to the pad instantly.You have to just touch the joint for an INSTANT and immediately pull away. Anything longer will destroy the LED.So both surfaces have to be tinned, the iron tip has to be clean and tinned, with just a tiny micro drop of wetted solder hanging on the tip.I admit, it's tedious. But it does work.However, there are now so many cheap sources of 0603 and 0402 LEDs with pre-soldered leads, that I do avoid this task if at all possible.
... Max mentioned in another thread a solder that instantly solidifies. ...
Eutectic solder. I don't know if Max's recommendation is a lead-free alloy, but I use 63/37 tin/lead. Crucial for tiny stuff where you need to hold your breath while the joint cools.
And for the record... it wasn't me... It was Peteski who has alerted us to the importance of using that solder. I confess that I still do not have any.Notice... I stick the wire down to the double-sided tape WITH the LED, as I described. Then I don't have to hold it, nothing moves, and I can just touch with the iron, pull away, and the joint cools however it has to without being disturbed by clumsy fingers.As for the pre-wired LEDs on eBay... here is one that I like:https://www.ebay.com/itm/10pcs-0402-SMD-LED-Warm-White-Pre-wired-micro-litz-wired-Soldered-20CM-Line/292783752859?ssPageName=STRK%3AMEBIDX%3AIT&_trksid=p2060353.m1438.l264910 warm white 0402, prewired, for under 8 bucks. Yes, you can do it cheaper if you buy them in bulk, unwired, and solder yourself. I just don't use enough of them to make that worthwhile.
Unfortunately, I have not found any pre-wired with 38 gauge green and red magnet wire, which I really like for threading into small holes.