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I have used 3mm MDF with great success. 30mm, (12 inch) radius corners were no trouble and it takes paint very well. Not as heavy as Masonite and so much easier to form corners.In the new garage I just painted right on the wall and curved the corners with styrene, again with 30mm radius corners. It took paint very well and the seam is so thin it is hardly noticeable. (Attachment Link) Rod.
Now, I’ve never tried this and was wondering if anyone has. Using sheet vinyl, the type used on floors.I’m thinking the supporting, priming, painting and joining seams would be a challenge.
I used Masonite which was wiped with a clean moist towel to clean it before I painted the backdrop with latex paint. No problems over 28 years with room temperatures in that out-back shed ranging from 25 degrees to 110 degrees F. 'Used flathead screws and drywall mud. Seams were drywall joint paper but a few came loose after about 10 years and I had to redo with the fiberglass mesh, which worked very well. I was well pleased and am using Masonite again on the new layout which is under construction.