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I'm pretty sure I can't bake the paint, in part because there is some styrene in model, but also because it was assembled with CA.
I would use primer first. As dark of a primer as you can find for the black and white primer for the orange.For bare metal I usually get a can of self-etching primer at an automotive body supply shop. But for N scale work, I decant it and spray it through an airbrush. That way I have much better control of the paint volume and direction. That would make spraying all the crevices in a bridge easier (without flooding all the surrounding areas with too much paint).