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I have used it for roads and a scrap yard. I used a little white glue underneath to hold it in place, then I used a wetwater mist and the grout dried solid. You might want to reach out to @Ed Kapuscinski . He is a big fan of using grout and used it in his yard.Here is his article on it http://conrail1285.com/n-scale-ballast-using-sanded-grout/
I painted the underlying surface with a shade of paint close to the grout. (this was for a flat dirt area in a yard).When the paint dried, I brushed thinned carpenter's glue over the area and dusted grout over the top. After if dried, I vacuumed up the excess (which was minimal). I think there were a few spots where I had to brush on some more thinned glue and dust more grout, but overall, it all came out well on the first application. It has held great for over a year now (maybe 2?). And because there's no glue or spray over the top of the grout, it has that bone-dry dirt look I was going for.
Grout looks like a terrific medium for roads and lots. I'm intrigued! Regarding its use ballast: when alcohol/water is applied, does the grout mix into a slurry, and end up looking like a solid mass, or does it retain an "aggregate-y" look? I suppose I could get off my intellectual a$$, and go read the article that Ed was kind enough to write.-Joe