You're welcome Craig.
I also suspect that the 450 max temperature in in Celsius, because that temperature in Fahrenheit is at the very low end of solder melting temps.
450C is 842F . Way too hot for precision soldering! That also explains why the tip burned (oxidized) quickly needing to be revived.
I usually keep mine between 600-700F (343-371C). I use electronic solder (63/37), but most industrially made electronics use lead-free solder where I have crank the temp up to about 740F (393C)
I know you like to use hot iron, but for soldering small SMD LEDs, that can lead to damage. I recommend the 63/37 solder and 650F temperature for small components. Higher temps make sense when soldering larger components or larger copper areas on a PC board. Also the tip size is important. Small tip doesn't have a enough heat transfer capacity for transferring heat to the solder joint, but it is perfectly adequate for the tiny solder pads on a 0201 LID. If used on a larger components, the tip will simply not have enough thermal transfer capacity to make a good joint. For those jobs a larger tip is needed.