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For PVC,I'd use glue for PVC pipe.See no reason it wouldn't work just as well on Styrene,it's sold in fairly large cans.If how it looks is no issue,they also sell a primer that's purple that makes the joint even stronger..
PVC glues tend to be a very thick and sloppy in application. This is as much a function of the hidden nature of the joints and pervasive need of function over form. Pretty and clean is no better than ugly as sin, but still works properly. Nobody cares much that there is a purple stain and lumpy glue blobs on underground sprinkler joints or hidden under your sink. You might actually care about such things on a scale model...
Im looking for the strongest glue to attach PVC to Styrene currently Im using Plastruct or Tenex solvents, are those the strongest for my particular application. One last question I hate working with 2 oz bottles of that stuff where can I get larger quantities of Tenex solvent.
I bought a pint of MEK and a pint of toluol at my local hardware store for less than $7. I mix 80 MEK to 20 toluol in a 3 oz bottle, and it works better than any glue I've ever bought. The mix isn't very critical. I keep the two cans tightly sealed in a far corner of a large garage, and am very careful pouring. The MEK alone will weld plastic; the toluol just adds some tackiness and slows the drying.