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Eutectic solder. I don't know if Max's recommendation is a lead-free alloy, but I use 63/37 tin/lead. Crucial for tiny stuff where you need to hold your breath while the joint cools.
Here are several ways.Paint the entire inside of the headlight housing white (before installing the LED). That will nicely bounce the light and will make the entire headlight appear to glow (not just the LED). Silver paint will do that too, but to a much lesser extent. White is best.Punch a disk from 0.005" white styrene and use as a headlight front cover. That is translucent, and will diffuse the light. But it will be white in color.Take a piece of clear styrene sheet (0.005" or 0.010") and sand one side using 400 or 600 grit sandpaper. Then punch a disk out and use as headlight cover. Mix some talcum powder into your Krystal Clear and fill the headlight housing with it (will take some time to cure). That will make it milky and it will diffuse light. Any translucent milky/frosty material will do that.Or use one of the UV-curable clear resins (like Bondic), again with some talcum powder mixed-in to fill the headlight housing. Depending on how deep the headlight housing is, I would probably do this in multiple layers (the talcum powder might block some of the UV light, slowing down the cure.
I wouldn't use silver solder, doesn't that use acid flux? In the past I bought micro LEDs and tried to solder leads to them, and in spite of me being great at soldering, it was VERY HARD to do. Now I buy the LEDs with the leads already attached but what worked best was to use solder paste. Line everything up (LED and wire), apply a dab of paste with a toothpick, heat with the iron (just heat, no need to actually touch the LED or wire), let cool, done. Good luck!
Thanks for the great ideas! Are there any milky coating materials you would specifically recommend that don't need to be mixed? I don't have any talcum powder on hand, and I have a Hobby Lobby about a mile down the road.