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Machining will be absolutely necessary regardless of material. 3D printing processes simply are not capable of the precision roundness needed for wheels, and John already mentioned the relative imprecision with the standard post-printing processes. I guess it would be possible to make rough billets this way, but you would still need to chuck them into a lathe for final profiling and roundness.See Max's thread about turning tires on a scratchbuilt steamer, among a zillion other "do it this way for best results" examples.
John, I have to disagree with you about brass being too soft. Majority of N scale metal wheels are made from brass - sometimes even unplated - just blackened. The Walthers Mallet's tender wheels are just blackened brass. Most manufacturers do plate the brass wheels with some silver color metal - possibly nickel-silver or nickel. But that plating wears off, exposing the brass colored metal underneath it. Atlas locos are a prime example. I have lots of those wheel-sets where the tread is brass-color. But Kato wheels do not seem to show any brass color, even on wheels with lots of wear. I wonder if they use nickel-silver for the wheels.
Ok can't argue with that but a driven wheel takes a lot more abuse than a non-driven wheel.There is a reason that Max plated his brass driver tires in Nickel.
@CVSNE, That was a very interesting article, thank you! I'll be sure to check the Proto:48 page for more cool stuff. Originally I was planning on having Shapeways do them in brass, and doing an interference fit by heating the tire up like on the prototype, however this thread makes me unsure that that would be an option. Does anyone know if Shapeways brass parts are cast or sintered like the stainless steel? Also, do you guys think a FUD/FXD wheel center would work? (Albeit, it would kind of negate the whole thing about building a brass engine, but I digress.) What about resin casting?I know I'm probably asking a lot of silly questions, but I'm new to this and I'm the kind of person who likes biting off a little more than they can chew. Life's more fun that way.
Brass is done using the lost-wax casting method. For all the details see https://www.shapeways.com/materials/brass . I highly recommend that you go to the materials landing page https://www.shapeways.com/materials then click on each material you are interested in. Al the technical details and production details are provided there for each.