I have connected to the brushes before and checked for repetitive resistance measurements as the armature is rotated. If there is an open coil, there will be a fairly gross difference in resistance at that spot but, I don't like doing it that way. It doesn't seem to be conclusive enough. Checking adjacent segments is the best way. As Pete indicated, if you have to give the armature a manual start sometimes, something is certainly wrong.
About the only other thing that can cause that symptom is if there are spots on the commutator segments that are dirty and the brushes aren't making reliable contact. You would have to disassemble the motor enough to check that out, too, or, I have stuck toothpicks soaked in Lacquer thinner against the armature while it is turning to scrape off contaminants but it has to be a motor where you have access to the commutator. That's not usually the case with modern motors (mine have been the motors used in Treble-O-Lectric locos).
Doug