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What size is your final layout? If it's < 2x4 feet, you won't need the pine frame.
BTW...what type of glue are you using to laminate the two layers?
Yeah, we played with Sintra on the new HO Modutrak layout for roadbed material. It's not a laminate like gatorfoam, but rather a solid PVC sheet. Well, not solid like a PVC pipe, it has enough air pockets to allow easy spiking, which was a need for handlaying HO track.
Sintracould give great annoyance when applying scenery. It has a closed surface with no open cells for water based methods to adhere to. I like the 6mm a lot for backdrops where commercial spray adhesives can be effectively used to bond printed materials to it. 20+ years ago I built a HO layout on foamcore (gatorboard) and it was loud as could be, but remarkably stable in a SoCal garage without temperature controls. With either of these a layer of cork would be suggested to reduce sound transmission...